-------------------------------- S1g. Quantum-classical mechanics -------------------------------- Quantum mechanics and classical mechanics are very close relatives. There are analogous objects for everything of relevance in classical and quantum statistical mechanics. Observable f: classical - real phase space function f(x,p) quantum - Hermitian linear operator or sesquilinear form f Lie product f \lp g: read \lp as 'Lie', and visualize it as inverted, stylized L; Macro for LaTeX: \def\lp{\mbox{\Large$\,_\urcorner\,$}} classical: f \lp g = {g,f} in terms of the Poisson bracket quantum: f \lp g = i/hbar [f,g] in terms of the commutator The Lie product is bilinear in the arguments and satisfies f \lp g = - g \lp f f \lp gh = (f \lp g)h + g(f \lp h) (Leibniz) f \lp (g \lp h) = (f \lp g) \lp h + g \lp (f \lp h) (Jacobi) Invariant measure: classical - integral f := integral dxdp f(x,p) quantum - integral f := trace f Integrability: integral |f| finite quantum integrable <==> f trace class Partial integration formula: integral f \lp g = 0. Dynamics: df/dt = X_H f := H \lp f with Hermitian H canonical transformations = mappings exp(tX_H) with Hermitian H Liouville's theorem says that integral f = integral exp(tX_H)f The infinitesimal form of this is the partial integration formula. State rho: classical - real integrable phase space function rho(x,p)>=0 quantum - Hermitian positive semidefinite trace class operator rho both normalized to integral rho = 1. expectation of f in state rho: = integral rho f